Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1237991 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2009 | 5 Pages |
Abstract
New stable Fe(III) complexes of tetraamide [N6], [N8] and [N10] macrocyclic ligands are reported. One of them, [N10] is dinucleating, with two Fe(III) nuclei in the macrocyclic cavities. The structural features have been discussed on the basis of analytical, ESI mass, FT-IR, electronic, 1H and 13C NMR spectral studies. Magnetic moment studies indicate presence of anti-ferromagnetically coupled (Fe3+–Fe3+ = S5/2–S5/2) spin–spin interactions in the dinuclear [N10] complex. 57Fe Mössbauer measurements confirm Fe(±3/2 → ±1/2) nuclear transitions supporting high–spin configuration of Fe(III) nuclei with the presence of Kramer's double degeneracy.
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Authors
Zafar A. Siddiqi, Sarvendra Kumar, Mohd. Khalid, M. Shahid,