Article ID Journal Published Year Pages File Type
1238136 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2008 6 Pages PDF
Abstract

Good quality single crystals of thiourea-doped triglycinesulphate (TuTGS) a new semiorganic nonlinear optical (NLO) crystal has been successfully grown from aqueous solution by slow evaporation method. The solubilities under various solvents in different proportions have been studied. The structural characterization of the grown crystals was carried out by X-ray diffraction. The grown crystals were subjected to FTIR and Raman analyses for vibrational assignments. The optical absorption coefficient α was analysed and interpreted to be allowed in the direct transition. The values of allowed direct energy gap (Eg) for undoped and doped crystals were calculated. It was found that Eg values were decreased with organic molecule doping. The powder technique of Kurtz and Perry confirm the NLO property of the grown crystal.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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