| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1238174 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2008 | 4 Pages |
Abstract
The infrared absorption spectra of the carbonyl stretching vibrations of 6-methylcoumarin (6MC) have been investigated in CCl4/ROH mixtures (CCl4/C2H5OH, CCl4/n-C3H7OH, CCl4/i-C3H7OH, and CCl4/t-C5H11OH). Two types of carbonyl stretching vibration bands for 6MC are found with the change of the mole fraction of the aprotic solvent CCl4(XCCl4) in binary solvent mixtures. The dependencies of the frequencies of carbonyl stretching vibrations Ï
(CO) on XCCl4 allow a distinction and assignment of all species resulting from the solvent-solute interactions. Linear correlations between the Ï
(CO) of each species and XCCl4 are found. The influence on the transformation of some species caused by the self-associated alcohols is discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Feiying Zhang, Hui Zhang, Danjun Fang, Qing Liu,