Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1238443 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2007 | 7 Pages |
Abstract
We have studied micelles comprised of cationic (CTAB) and anionic (SDS) surfactants through the interactions of solution phase anionic disodium fluorescein (DSF) and cationic rhodamine 110 (R110) dyes with perylene sequestered within the micelles. Fluorescence lifetime measurements monitor energy transfer between the nonpolar optical donor within the micelle and ionic probes in the surrounding solution. The efficiency of this process is mediated by the extent to which the ionic dyes interact with the micelle palisade layer, and our fluorescence lifetime data allow us to determine the association constants for acceptor-micelle interactions.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Sarah A. Stevenson, G.J. Blanchard,