Article ID Journal Published Year Pages File Type
1239421 Spectrochimica Acta Part B: Atomic Spectroscopy 2016 5 Pages PDF
Abstract

•Spatially-offset double-pulse (SODP) LIBS is invented for analysis of thin layers.•A spatial offset by a few mm between two laser spots is the key in this technique.•It is demonstrated that SODP-LIBS is superior to the standard collinear DP-LIBS.

A novel technique, spatially-offset double-pulse laser-induced breakdown spectroscopy (SODP-LIBS), is invented for analysis of thin layers. In this technique, two laser spots are spatially offset by a few mm, while there is no spatial gap for the standard collinear DP-LIBS. It is demonstrated from analysis of thin W layers (∼30–250 nm thickness) deposited on Mo substrates at a reduced ambient pressure of ∼ 5 × 10 −3 Torr that (1) the W I signal intensity is enhanced with SODP-LIBS and (2) a clearer transition between W and Mo is obtained with SODP-LIBS, compared to the standard DP-LIBS.

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Physical Sciences and Engineering Chemistry Analytical Chemistry
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