Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1240015 | Spectrochimica Acta Part B: Atomic Spectroscopy | 2011 | 8 Pages |
Abstract
⺠Arsane generation with aqueous tetrahydroborate in the presence of trace Au, Pd and Pt. ⺠Incorporation of hydrogen from the solvent into arsane. ⺠Au, Pd and Pt perturb the mechanism of hydrogen transfer from borane to As. ⺠Key-role played by metal-borane complex intermediates in the early stage of reaction.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Enea Pagliano, Massimo Onor, Juris Meija, Zoltan Mester, Ralph E. Sturgeon, Alessandro D'Ulivo,