A simplified calculation of power-broadened linewidths, with application to resonance ionization mass spectrometry

I present a simple derivation of the power-broadened linewidth of an optical transition in a two-level atom. The novelty of the approach lies in its flexibility, as the approach described here can be applied to any spectral lineshape, corresponding to either homogeneous or inhomogeneous broadening mechanisms. For a Lorentzian profile, I recover the same dependence of linewidth on laser power that one calculates from the optical Bloch equations. The present treatment makes explicit that power broadening arises because of the saturability of the atomic response to intense lasers, rather than to explicitly quantum mechanical aspects of the laser–atom interaction, all of which are ignored. I discuss the utility of power broadening in resonance ionization mass spectrometry, where it is an important means of mitigating unwanted instrumental isotope fractionation.

► A simple derivation of the power-broadened linewidth of an optical transition. ► Method accommodates lines that are homogeneously or inhomogeously broadened. ► Power broadening mitigates isotopic sensitivity to laser drift and jitter in RIMS.