A near-infrared-emitting CdTe/CdS core/shell quantum dots-based OFF–ON fluorescence sensor for highly selective and sensitive detection of Cd2+

A near-infrared-emitting CdTe/CdS core/shell quantum dots (QDs)-based photoluminescence (PL) sensor was designed and applied for highly selective and sensitive detection of Cd2+. This sensor was based on a PL “OFF–ON” mode. First, the addition of ammonium pyrrolidine dithiocarbamate (APDC) led to remarked PL quenching of QDs. Second, PL of APDC surface modified QDs (QDs-APDC) was gradually restored with the each increment of Cd2+ concentration. Experimental results showed that PL of QDs-APDC was near proportional upon the addition of Cd2+ in the range from 0.1 to 2 μM with a good correlation coefficient of 0.9989. The limit of detection of this proposed method was 6 nM. Interferential experiments confirmed that this sensor of Cd2+ was highly selective over other metal ions. To further investigate perfect analysis performance, this sensor was favorably utilized to determine Cd2+ in tap water, river water and liposome solutions.

► A near-infrared-emitting quantum dots-based fluorescence sensor was developed to detect Cd2+. ► This sensor was based on a fluorescence “OFF–ON” mode. ► The limit of detection was 6 nM. ► Interferential experiments confirmed the high selectivity of this sensor.