Article ID Journal Published Year Pages File Type
1247386 Talanta 2006 5 Pages PDF
Abstract

The performance of a new graphite–castor oil polyurethane composite electrode in the determination of hydroquinone in photographic developers in a differential pulse voltammetric (DPV) procedure is described. The 60% (graphite, w/w) composite electrode presented good stability, repeatability and accurate response. Limit of detection of 934 nmol L−1 was observed for hydroquinone within a linear dynamic range from 66 to 530 nmol L−1. The determination of hydroquinone in a photographic developer sample showed agreement with the label values in a 95% confidence level with maximum 2% relative error and recoveries between 100.1 and 100.4%. No need of sample preparation was required since the p-methylaminophenolsulfate (metol) present in the developer formulation did not interfered in the measurements.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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