Derivatization techniques for determination of carbonyls in air

•To quantify ambient carbonyls, derivatization is employed in sampling and detection.•Common derivatization techniques have shortcomings as sources of bias.•Up-to-date review of progress in derivatization for carbonyl compounds in air.

This review critically assesses the derivatization techniques employed in sampling and detection of carbonyl compounds in air. We explore the most common techniques reported for the collection of vapor- phase carbonyl compounds by focusing on the hydrazine-derivatization techniques developed with the aid of diverse sorptive media [solution (e.g., in impingers), solid sorbents, solid-phase extraction, solid-phase microextraction, and denuder, or other approaches]. We discuss the advantages and the disadvantages of each sampling and pretreatment option for key carbonyl compounds with reference to measurement data obtained under laboratory and field conditions.