Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1249636 | Vibrational Spectroscopy | 2012 | 5 Pages |
Abstract
We investigated an electrochemical reaction on the cathode surface of an overcharged Li[Ni0.45Co0.18Mn0.25Al0.12]O2/Li system at the molecular level by using Raman, X-ray absorption spectroscopy (XAS), and 2D hetero-spectral correlation analyses. Changes in the Raman spectra during the overcharging process showed that variations in the local atomic environment occurred with increasing extraction of Li+ ions. XAS spectra obtained during the overcharging process showed that oxidized transition metals coexisted with inoxidizable transition metals. Additionally, synchronous 2D hetero-spectral Raman/XAS correlation spectra clearly elucidated the correlation between the Raman and XAS bands, confirming their band assignments.
Related Topics
Physical Sciences and Engineering
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Analytical Chemistry
Authors
Yeonju Park, Nam Hoon Kim, Hyun Chul Choi, Sung Man Lee, Hoon Hwang, Yeon Uk Jeong, Young Mee Jung,