Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1250084 | Vibrational Spectroscopy | 2006 | 7 Pages |
Abstract
Ab initio harmonic B3LYP/6-31G* derived force fields were used to perform normal mode analysis for the most stable monomers and dimmers of neat 2-methoxyethanol (ethyleneglycol methyl ether) and of 2-methoxyethanol/acrylamide solutions. An interpretation of the Raman spectra for the neat 2-methoxyethanol and its solutions with acrylamide were analysed and associated to the monomeric and dimeric species intermolecular interactions either in the neat compound or in the mixtures with acrylamide in terms of intra- and intermolecular hydrogen-bonded and steric effects.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
A.M. Amorim da Costa, A.S.R. Duarte, A.M. Amado,