Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1250122 | Vibrational Spectroscopy | 2006 | 10 Pages |
Abstract
FT-Raman spectroscopy has been used to study the group-transfer polymerisation (GTP) of methyl methacrylate in tetrahydrofuran solvent with a tetrabutylammonium acetate catalyst at â65 °C. Although the spectroscopic study of the polymerisation of vinyl monomers has been reported hitherto, this is the first time that a GTP process has been studied quantitatively in this way. The in situ Raman spectroscopic monitoring of the band intensity of the 1638 cmâ1 (CC) stretching mode of the methyl methacrylate monomer consumption with time using a remote fibre optic probe has enabled the evaluation of the rate constant of the reaction to be made. Comparison is effected with calculations carried out on the polymer propagation using a mechanistic kinetic model incorporating heat transfer data and refinement to the experimental data to estimate the activation energy of the reaction.
Related Topics
Physical Sciences and Engineering
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Analytical Chemistry
Authors
H.G.M. Edwards, K.S. Johal, A.F. Johnson,