Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1250600 | Vibrational Spectroscopy | 2011 | 9 Pages |
Abstract
Using Raman, terahertz (THz), and mid-infrared (IR) spectroscopies, the vibrational spectra of two chromophore models of hydrogen-producing [FeFe]-hydrogenase, Fe2(μ-S2C3H6)(CO)6 and Fe2(μ-S2C2H4)(CO)6, have been assigned. The combination of absorption and scattering techniques, along with DFT calculations, allows for assignments to be made without traditional isotopic substitution methods.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Christopher J. Stromberg, Casey L. Kohnhorst, Glenn A. Van Meter, Elizabeth A. Rakowski, Benjamin C. Caplins, Tiffany A. Gutowski, Jennifer L. Mehalko, Edwin J. Heilweil,