| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1251222 | Chemical Research in Chinese Universities | 2007 | 4 Pages |
Abstract
The organo-inorganic hybrid compound [Ni(phen)3] [(H2W12O40) {Ni(phen)2H2O} {Ni(trien)}] · 2H2O was synthesized from Na2WO4, · 2H2O, NiSO4 · 6H2O, CH3COOK, triethylenetetramine and 1,10-phenanthroline in water by the hydrothermal reaction, and characterized by IR, X-ray single crystal diffraction, and TG-DTA analysis. This compound crystallized in the monoclinic system, space group P2 (1)/n, with lattice constants: a = 1. 80998(6) nm, b = 2. 36504(8) nm, c = 2. 29199(7) nm, β = 110. 2220(10)·, V = 9. 2065(5) nm, Z = 4. Final R indices R1 = 0. 0532, wR2 = 0. 1295. The compound is decomposed at 593 °C.
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Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
LIU Kun, MENG Fan-xia, MA Feng-xia, CHEN Ya-guang,