Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1251433 | Chemical Research in Chinese Universities | 2006 | 4 Pages |
Abstract
Ag+-doped ZnS nanocrystals surface-capped with thiourea (expressed as ZnS: Ag/thiourea) were synthesized through sol-gel method with thiourea as a surface modifier and characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), X-ray fluorescence spectrum (XRF), infrared spectrum (IR), UV-Vis absorption spectrum(UV-Vis), and photoluminescence spectrum (PL). The results show that Ag+ ions are doped in ZnS nanocrys-tals, and the sulfur atoms in thiourea molecules coordinate with metal ions on the surface of the nanocrystals. The spherical ZnS: Ag/thiourea nanocrystals with an average diameter of 5 nm have good fluorescent characteristics, and therefore have great potential for use in molecular assembly and novel luminescence materials.
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Authors
HUANG Feng-hua, PENG Yi-ru, LIN Cheng-fang,