Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1253082 | Chemical Research in Chinese Universities | 2006 | 5 Pages |
Abstract
A bis-benzospiropyran(BBSP) and nitro-substituted indoline spirobenzopyrans(SBP) were prepared by following a simple procedure. The reaction mechanism of synthesizing bis-benzospiropyran is discussed. A comparative analysis of the spectral and photochromic properties between SBP and BBSP was carried out with the aid of a PMMA film. The results indicate that chemical structures and UV irradiation played an important role in the spectral and photochromic properties of SBP and BBSP, which would readily affect λmax of the colored forms and the reversibility. The IR spectra and 1H NMR spectra of these compounds are used to interpret the photochromic phenomena under different UV irradiation and determine the configurations of SBP and BBSP.
Related Topics
Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
SHEN Kai-hua, HAN Jian-guo, ZHANG Gang, CHOI Dong-hoon,