Phase diagram of Er-Sn-Te system for diluted magnetic semiconductor developments

Phase diagrams of the RE (rare earth)-IV-VI systems are very important for the design of rare earth doped diluted magnetic semiconductors (DMSs), but related information is very limited. In this work, the phase equilibria of the Er-Sn-Te system in whole compositional range at room temperature were investigated mainly by means of X-ray powder diffraction (XRD) and differential thermal analysis (DTA). The existences of 9 binary compounds, i.e., SnTe, ErTe3, Er2Te3, ErTe, Er5Sn3, Er11Sn10, ErSn2, Er3Sn7 and Er2Sn5 were confirmed. The phase diagram consisted of 12 single-phase regions, 21 binary phase regions and 10 ternary phase regions. The maximum solid solubility of Er in SnTe was determined to be about 7.5 at.%, none of the other phases in this system revealed a remarkable homogeneity range at room temperature. No ternary compound was found in this work.

Graphical abstractIsothermal section of the Er-Sn-Te ternary system at room temperatureFigure optionsDownload full-size imageDownload as PowerPoint slide