Article ID Journal Published Year Pages File Type
1259949 Journal of Rare Earths 2015 6 Pages PDF
Abstract

Ca12Al14O32F2:Eu3+ red phosphors were prepared by the sol-gel method with CF3COOH as the fluorine source. X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectra, and photoluminescence spectra, as well as thermogravimetric and differential thermal analysis were utilized to characterize the samples. All the samples were single phase with a cubic structure. The as-obtained Ca12Al14O32F2:Eu3+ red phosphors consisted of nanoparticles with sizes of approximately 40–100 nm. Under the excitation of UV light, Ca12Al14O32F2:Eu3+ exhibited the characteristic emissions of Eu3+, and the effect of annealing temperature, annealing time, and CF3COOH and Eu3+ concentrations on the luminescence intensity were discussed in detail.

Graphical AbstractTGA-DTA spectra of dried gel (temperature rate: 10 °C/min, instrument: SDTQ 600)Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)
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