Investigation of the red-shift of the emission of microwave solvothermally-grown europium doped calcium sulphide crystals

A distinct red-shift to 660 nm-featured longer wavelength of europium doped calcium sulphide nanocrystals was observed in a microwave (MW)-assisted solvothermal synthesis procedure. This red-shift was probably due to a combined effect from Mg2+ codoping and strain accumulation at grain boundaries. The latter originated from the formation of small grains with an average size of around 200 nm in micrometer sized crystals upon Mg2+ codoping. In particular, MW electromagnetic field suppressed grain growth and enabled a reconstruction of atoms at the inner grain boundary at which the field strength was intensified around rare earth ions in host lattices. This MW synthesis route provided an option to prepare luminescent crystals with the desired blue-excitable longer wavelength emission.

Graphical AbstractPLE monitored at 660 nm and PL excited at 450 nm of Ca0.994–xMgxS:0.004Mn2+, 0.002Eu2+ (x=0.1, 0.2, 0.3, 0.4, 0.5) crystals prepared by microwave-assisted solvothermal synthesis procedureFigure optionsDownload full-size imageDownload as PowerPoint slide