Article ID Journal Published Year Pages File Type
1262436 Journal of Rare Earths 2011 4 Pages PDF
Abstract

Er3+ and Li+ codoped Y3Al5O12 (YAG) powders were prepared for a systematic investigation of their upconversion emissions. X-ray diffraction (XRD), upconversion emission spectra, pump power dependence, FT-IR spectra and decay time were studied to characterize the samples. With Li+ doping, the upconversion emission intensity of Er3+ doped YAG powders was obviously enhanced, accompanied with an increase in the ratio of green to red intensity. The enhancement of emission intensity could be attributed to two mechanisms: one was the distortion of local crystal field around Er3+, and the other was the decrease in the amount of CO32− and OH− groups. Our results revealed that the latter was the dominant mechanism of the upconversion intensity enhancement in the YAG:Er3+/Li+ powders.

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Physical Sciences and Engineering Chemistry Chemistry (General)