Article ID Journal Published Year Pages File Type
1262495 Journal of Rare Earths 2011 5 Pages PDF
Abstract

Polycrystalline Nd0.75Na0.25Mn1-xCrxO3 (0=x=0.1) samples were prepared by sol-gel method and their magnetic and electrical transport properties were investigated experimentally. The parent compound with x=0 was a charge ordered manganite and the charge ordering transition occurred at 170 K. For lower Cr concentration (x<0.03), the samples preserved the charge ordering features of the parent compound, but the charge ordering transition temperature decreased with increasing x, in particular from 170 K for x=0 to 154 K for x=0.02. For the x≥0.03 samples, paramagnetic to ferromagnetic phase transition took place and the Curie temperature increased from 112.8 K for x=0.04 to 125.5 K for x=0.1. The electrical transport properties were also influenced by Cr doping. For x<0.03, the samples displayed insulator characteristics below 300 K. For x=0.04, the sample showed insulator-metal transition around 75 K. For x≥0.05, the insulator-metal transition disappeared and the compounds showed insulator features again. The magnetic and electrical properties could be well explained by the phase separation scenario.

Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)