Dissolved titanium distributions in the Mid-Atlantic Bight

Although titanium is abundant in Earth's crust, its sources and distribution in the ocean are poorly understood. To elucidate its behavior, distributions of dissolved (< 0.2 μm) Ti were determined in surface waters and vertical profiles from the Mid-Atlantic Bight (MAB). Concentrations of Ti decreased from 390 pM at the Delaware Bay mouth to < 100 pM across the Delaware continental shelf. In vertical profiles, small increases in bottom waters suggest a possible flux of Ti from shelf sediments, consistent with previous reports of pore water enrichments of dissolved Ti in MAB sediments. Concentrations in surface waters of the outer shelf and slope ranged between 30 and 140 pM, with most values below 90 pM. Concentrations in a 1000 m vertical profile in the eastern Gulf Stream ranged between 110 and 280 pM, and showed a variable distribution attributed to the mixing of water masses in the outer MAB. A simple model of Ti sources to the MAB suggests that atmospheric deposition of dissolved Ti is comparable to net riverine contributions and therefore must be considered in applications of Ti as a tracer of oceanographic processes.