Article ID Journal Published Year Pages File Type
1264037 Organic Electronics 2012 6 Pages PDF
Abstract

In this study, we have successfully demonstrated a new system of donor–acceptor blend for bulk heterojunction solar cells of poly(3-hexylthiophene) (P3HT) by using vanadyl 2,9,16,23-tetraphenoxy-29H,31H-phthalocyanine (VOPcPhO) as acceptor material. A broad absorption over the whole visible range (450–750 nm) is achieved. Utilizing this blend system in solar cell fabrication, ITO/PEDOT:PSS/P3HT:VOPcPhO/Al solar cells have been fabricated and characterized in open air. A maximum power conversation efficiency up to 1.09% has been recorded. To confirm the charge transport, the electron and hole mobility of VoPcPhO has been measured. The results show that the VoPcPhO has bipolar transport and can act as an electron as well as hole transporting material. The electron mobility is comparable with hole mobility.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A new system of binary donor–acceptor blend. ► A broad absorption over the whole visible range (450–750 nm) is achieved. ► Maximum power conversation efficiency up to 1.09% has been recorded.

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Physical Sciences and Engineering Chemistry Chemistry (General)
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