Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1265409 | Ultrasonics Sonochemistry | 2012 | 5 Pages |
The hierarchically structured mesoporous LiMn2O4 (LMO) nanospheres were synthesized using a template-free self-assembly process that was coupled with ultrasound (U). The ultrasound technique suggested here is very powerful for controlling an ordered nanostructure and improving crystallinity with large single-crystalline domains. Owing to the hierarchical mesoporous structure and high crystallinity, U-LMO provides an excellent rate capability and cycle stability with a capacity retention of more than 98% up to 50 cycles at a 0.2 C rate. Here, we demonstrate that mesoporous U-LMO nanospheres were fabricated to enhance the electrochemical performance and protect it from structurally significant collapsing because of high crystallinity.
► Hierarchically structured mesoporous LiMn2O4 nanospheres. ► Simple and cost effective synthetic method using ultrasonic waves. ► Ultrasonic waves increase single-crystalline domain size and enhance crystallinity. ► Mesoporous nanostructures with high crystallinity can improve rate capability and cyclability.