Article ID Journal Published Year Pages File Type
1265426 Organic Electronics 2011 4 Pages PDF
Abstract

The improvement of current injection efficiency in organic light emitting diodes is demonstrated with incorporation of lithium fluoride (LiF) mixed with subphthalocyanine (SubPc) as electron injection layers. The photoemission spectra indicate that the lithium released from LiF would remove chlorine atoms from SubPc molecules and create large density of gap states at the interfaces. These gap states, resulted from the addition of SubPc in conventional aluminum/LiF/ tris-(8-Hydroxyquinoline)-aluminum (Alq3) cathode structures, further enhance the electron injection efficiency in OLEDs. The results demonstrate a relatively unique feature of SubPc which can be used to improve both electron and hole injection efficiency.

Graphical abstractThe improvement of current injection efficiency in organic light emitting diodes is demonstrated with incorporation of lithium fluoride (LiF) mixed with subphthalocyanine (SubPc) as electron injection layers. The photoemission spectra indicate that the lithium released from LiF would remove chlorine atoms from SubPc molecules and create large density of gap states at the interfaces. These gap states, resulted from the addition of SubPc in conventional aluminum/LiF/tris-(8-Hydroxyquinoline)-aluminum (Alq3) cathode structures, further enhance the electron injection efficiency in OLEDs. The results demonstrate a relatively unique feature of SubPc which can be used to improve both electron and hole injection efficiency.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► The improvement of current injection efficiency in organic light emitting diodes is demonstrated with incorporation of LiF mixed with SubPc as electron injection layers. ► Lithium released from LiF would remove chlorine atoms from SubPc molecules and create large density of gap states at the interfaces. ► SubPc can be used to improve both electron and hole injection efficiency.

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Physical Sciences and Engineering Chemistry Chemistry (General)
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