| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1270154 | Ultrasonics Sonochemistry | 2012 | 7 Pages |
An ultrasound-assisted method was used for synthesizing nanosized Pt–graphene oxide (GO)–TiO2 photocatalyst. The Pt–GO–TiO2 nanoparticles were characterized by diffused reflectance spectroscopy, X-ray diffraction, N2 BET adsorption–desorption measurements, atomic force microscopy and transmission electron microscopy. The photocatalytic and sonophotocatalytic degradation of a commonly used anionic surfactant, dodecylbenzenesulfonate (DBS), in aqueous solution was carried out using Pt–GO–TiO2 nanoparticles in order to evaluate the photocatalytic efficiency. For comparison purpose, sonolytic degradation of DBS was carried out. The Pt–GO–TiO2 catalyst degraded DBS at a higher rate than P–25 (TiO2), prepared TiO2 or GO–TiO2 photocatalysts. The mineralization of DBS was enhanced by a factor of 3 using Pt–GO–TiO2 compared to the P–25 (TiO2). In the presence of GO, an enhanced rate of DBS oxidation was observed and, when doped with platinum, mineralization of DBS was further enhanced. The Pt–GO–TiO2 catalyst also showed a considerable amount of degradation of DBS under visible light irradiation. The initial solution pH had an effect on the rate of photocatalytic oxidation of DBS, whereas no such effect of initial pH was observed in the sonochemical or sonophotocatalytic oxidation of DBS. The intermediate products formed during the degradation of DBS were monitored using electrospray mass spectrometry. The ability of GO to serve as a solid support to anchor platinum particles on GO–TiO2 is useful in developing new photocatalysts.
► A new photocatalyst, graphene oxide (GO) based Pt–TiO2 has been synthesized. ► A remarkable enhancement on the photocatalytic mineralization of a surfactant is achieved. ► The mineralization efficiency of the new catalyst is three times higher than Degussa Pt–25 TiO2. ► A strong interaction between Pt and GO during the reduction of Pt is responsible for the higher efficiency of the catalysts.
