| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1295438 | Solid State Ionics | 2014 | 10 Pages |
•Polycrystalline Ba0.90Zr0.90Fe0.10O3 −δ (BZF10) is synthesized via solid-state reaction.•XRD and TEM indicate BZF10 is mostly in pure phase.•BZF10 is electrochemically characterized by ECR and EIS.•BZF10 membrane displays high O2 permeability at 600–900 °C.•BZF10 is electrochemically and mechanically stable over all tests (> 1000 h).
This paper reports the synthesis, materials characterization, electrochemical and transport properties under O2-environments of an iron-doped barium zirconate perovskite (Ba0.90Fe0.10Zr0.90O3 −δ or BZF10), a mixed ionic-electronic conductor (MIEC). BZF10 powder was synthesized by solid-state reaction of the binary oxides and characterized using synchrotron X-ray diffraction (XRD). Analysis of the XRD patterns indicated the presence in the powder of a primary cubic perovskite phase with a lattice parameter 4.19 Å. The actual composition of the powder was measured using proton induced X-ray emission (PIXE). The powder was pressed and sintered into pellets and the fracture cross-section was then investigated by transmission electron microscopy (TEM). TEM analysis indicates a polycrystalline structure and the electron-diffraction pattern confirms the XRD results. The pellets, with attached electrodes, were investigated for electrochemical activity under dry oxidizing atmosphere using a combination of electrical conductivity relaxation (ECR) and electrochemical impedance spectroscopy (EIS) in the range of 600–800 °C and oxygen permeability between 600–900 °C. ECR indicates that both the chemical diffusion coefficient DV and the surface kinetic parameter k′ increase with increasing pO2. EIS suggests a primarily p-type semiconduction behavior explaining the dependence of electrical conductivity upon oxygen partial pressure. Separate gas permeation measurements confirm an oxygen permeability of 4.11 × 10− 11 mol/(m · s · Pa). BZF10 materials showed superior stability during the whole study (> 1000 h on stream).
