Article ID Journal Published Year Pages File Type
1295655 Solid State Ionics 2006 8 Pages PDF
Abstract

The electrical properties of pure Anatase are investigated by impedance spectroscopy as function of temperature and oxygen partial pressure. The experimental results are fully interpreted by point defect chemistry. A transition from predominant Schottky to Frenkel cation disorder is observed when the temperature increases and/or the oxygen partial pressure decreases. The reduction enthalpies are near those obtained for Rutile in previous studies.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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