Article ID Journal Published Year Pages File Type
1296936 Solid State Ionics 2008 6 Pages PDF
Abstract

It was shown in many literature sources that ionic conductivity of the LiTi2(PO4)3 compound was increased by several orders substituting Ti4+ ion by trivalent ions. In the case of substituting by La3+ there was no success to synthesize single phase material. The two phases were obtained and conductivity increased considerably. In the present work the substitution Ti4+ → La3++ Li+ in the LiTi2(PO4)3 system was studied by XRD, SEM, XPS, WDX, and impedance spectroscopy. The powder was prepared by solid state reaction with relative mixture of initial materials to obtain Li1 + xLaxTi2 − x(PO4)3 with x = 0.3, but the impurity of LaPO4 was detected by XRD. The ceramic samples were sintered with different sintering duration to check the influence of sintering on composition and electrical properties.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
Authors
, , , , , , , , , ,