Article ID Journal Published Year Pages File Type
1296968 Solid State Ionics 2008 4 Pages PDF
Abstract
Cu6PS5X (X = I, Br) solid electrolytes are obtained in nanocrystalline state by ball milling, their crystalline structure is studied and average crystallite size is estimated from X-ray diffraction. Essential low-frequency shifts of Raman scattering bands, their broadening and intensity decrease with crystallite size decrease are observed. The specific features of Raman scattering in nanometric solid electrolytes are explained within the known approaches based on the results obtained and in comparison with the bulk crystals.
Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
Authors
, , , , , ,