Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1297044 | Solid State Ionics | 2012 | 5 Pages |
Highly ion-conductive Li6PS5X (X = Cl, Br, I) Li-argyrodites were prepared through a high‐energy ball milling. Electrical and electrochemical properties were investigated. Ball-milled compounds exhibit a high conductivity between 2 and 7 × 10− 4 S/cm with an activation energy of 0.3–0.4 eV for conduction. These attractive properties were attributed to the spontaneous formation of crystallized Li-argyrodite during ball-milling. An optimization of milling time led to a conductivity of 1.33 × 10− 3 S/cm for the Li6PS5Cl phase with an electrochemical stability up to 7 V vs. lithium. An all solid state LiCoO2/Elec./In lithium ion battery using ball-milled Li6PS5Cl as electrolyte was successfully assembled, and its room temperature performance is reported.
► Revisited synthesis of sulfur-based solid electrolyte for all solid state batteries. ► Argyrodite phase formed by high-energy ball milling synthesis. ► Wide electrochemical stability window from 0 to 7 V vs. Li. ► High ionic conductivity of 1.33 × 10− 3 S/cm for ball-milled Li6PS5Cl sample at room temperature. ► Reversible capacity of 100 mAh/g using LiCoO2 in all solid state battery.