Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1298374 | Solid State Ionics | 2006 | 4 Pages |
Abstract
We have synthesized poly(ethylene glycol) (PEG)-aluminate ester as a plasticizer for solid polymer electrolytes. The thermal stability, ionic conductivity and electrochemical stability of the polymer electrolyte which consist of poly(ethylene oxide) (PEO)-based copolymer, PEG–aluminate ester and lithium bis-trifluoromethanesulfonimide (LiTFSI) were investigated. Addition of PEG–aluminate ester increased the ionic conductivity of the polymer electrolyte, showing greater than 10− 4 S cm− 1 at 30 °C. The polymer electrolyte containing PEG–aluminate ester retained thermal stability of the non-additive polymer electrolyte and exhibited electrochemical stability up to 4.5 V vs. Li+/Li at 30 °C.
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Authors
Yuki Masuda, Masayuki Seki, Masanobu Nakayama, Masataka Wakihara, Hidehisa Mita,