Article ID Journal Published Year Pages File Type
1299645 Coordination Chemistry Reviews 2013 36 Pages PDF
Abstract

The design of metallogelators and incorporation of metals into supramolecular gels have received growing attention. Design strategies have been developed based on organogelators, including the incorporation of metal into low molecular weight organogelators (LMWGs), and coordination polymers assisted by auxiliary moieties (including lipophilic and hydrogen-bonding groups) as gelators. Additionally, a novel class of metal-organic gels lacking auxiliary moieties has recently been developed; these coordination-directed (induced) gels display novel properties e.g., in adsorption and catalysis and as templates for porous materials. This review highlights the design and properties of a diverse range of metallogelator types.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (203 K)Download as PowerPoint slideHighlights► Two general classes of metallogels developed including molecular metallogels and coordination polymer gels. ► Coordination polymer gelators developed assisted by auxiliary moieties. ► Metal-organic gelators developed lacking auxiliary moieties. ► Metal-organic gels with novel properties in adsorption, catalysis and as templates for porous materials.

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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