| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1299784 | Coordination Chemistry Reviews | 2015 | 27 Pages |
Abstract
- The term “carbones” for compounds with a C(0) atom stabilized by neutral donors is elucidated.
- The electronic situation of carbones as Ï and Ï donors is discussed.
- Main group Lewis acids A as acceptors cover electron deficient species from group 2 and groups 13-17 elements.
- Main group addition compounds of a series of different carbones are reviewed.
- Carbones comprise mainly carbodiphosphoranes, carbodicarbenes, and tetraaminoallene.
Keywords
TAA4-dimethylaminopyridineFLPDMAPNHCTMADCMDppmTHFEDANBODMEFrustrated Lewis pairDFTDMSON-heterocyclic carbeneHomohighest occupied molecular orbitalBipyridineTetrahydrofuraneEnergy decomposition analysisbipyDimethoxyethaneDichloromethaneDimethylsulfoxideNatural Bond OrbitalDensity functional theoryproton affinityPyridine
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Wolfgang Petz,