Article ID Journal Published Year Pages File Type
1299891 Coordination Chemistry Reviews 2015 26 Pages PDF
Abstract

•Oxo-molybdenum and oxo-rhenium complexes as good catalysts for deoxygenation reactions.•Methods for reduction of sulfoxides, nitro compounds, epoxides, N-oxides and alcohols.•Oxo-rhenium complexes as excellent catalysts for deoxygenation of biomass resources.

The deoxygenation of organic compounds is a fundamental process in both chemistry and biology and the development of new efficient methodologies for the synthesis of deoxygenated compounds is highly desired. Among the variety of catalysts used in the deoxygenation of organic compounds, high-valent oxo-molybdenum and oxo-rhenium complexes have attracted considerable interest. This review highlights the development of efficient methods for the deoxygenation of different classes of organic compounds such as sulfoxides, aromatic nitro compounds, N-oxides, epoxides, alcohols and polyols catalyzed by oxo-molybdenum and oxo-rhenium complexes.

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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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