Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1300749 | Coordination Chemistry Reviews | 2006 | 28 Pages |
Abstract
In this review are highlighted the key advances that have occurred in the discovery and development of 2,6-bis(imino)pyridyl iron(II) and cobalt(II) catalysts for the transformation of ethylene into linear and branched homopolymers or into α-olefins with either Schulz–Flory or Poisson distribution. Particular attention has been paid to studies of the electronic and geometrical structure of both supporting ligands and metal complexes as well as to the mechanisms of precatalyst activation, chain-propagation and chain-transfer.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Claudio Bianchini, Giuliano Giambastiani, Itzel Guerrero Rios, Giuseppe Mantovani, Andrea Meli, Anna M. Segarra,