Recent advances in Î·2-disilene and Î·2-disilyne mononuclear transition metal complexes and related compounds

Article ID	Journal	Published Year	Pages	File Type
1300833	Coordination Chemistry Reviews	2016	30 Pages	PDF

Abstract

- Synthesis and molecular structures of Î·2-disilene and Î·2-disilyne mononuclear complexes are discussed.
- Structural parameters and 29Si resonances of Î·2-disilene and Î·2-disilyne mononuclear complexes are comprehensively tabulated.
- Related transition metal complexes with Î·2-dimetallenes of heavy group-14 elements are briefly summarized.

Keywords

TFA DPPE Silene Disilene Disilyne Xyl DCD Cyclohexyl tert-butyl 2,6-Dimethylphenyl DMAP i-Pr THF NBO NICS DME η5-cyclopentadienyl Møller-Plesset η5-pentamethylcyclopentadienyl nuclear magnetic resonance 1,2-Bis(diphenylphosphino)ethane 1,2-Dimethoxyethane 1,5-Cyclooctadiene 2,4,6-triisopropylphenyl 4-(Dimethylamino)pyridine Cp*DFT Trifluoroacetate isopropyl Tetrahydrofuran NMR Nucleus independent chemical shift t-Bu phenyl Infrared Methyl Natural Bond Orbital Molecular orbital MeS Mesityl Density functional theory TIP Hartree-Fock X-ray diffraction XRD Transition metal complex Cod