Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects

Article ID	Journal	Published Year	Pages	File Type
1300852	Coordination Chemistry Reviews	2016	153 Pages	PDF

Abstract

- Manganese is a good metal for catalysis due to its abundance and biocompatibility.
- Manganese organometallic complexes do catalyze a broad variety of reactions.
- Mn catalysts can provide improved chemoselectivity and functional group tolerance.

Keywords

HmpA TMP Glc TBS TMS TOF TOL dpm THP AcAc DEC NMO Cyclohexyl TFE DIPP TOS trimethylsilyl NMP HEPT PHMS N-methylmorpholine-N-oxide n-butyl methoxymethyl DMPU p-toluenesulfonyl DME CPE TMEDA t-butyldimethylsilyl Hydrosilylation DCE Cp′N-Methylpyrrolidone 2,6-diisopropylphenyl DMF η5-cyclopentadienyl 1,10-Phenanthroline 1,2-dichloroethane 1,2-Dimethoxyethane 2,2,2-trifluoroethanol 2,2,6,6-Tetramethylpiperidine 2,2,6,6-Tetramethylpiperidine-1-oxyl DMSO N,N,N′,N′-tetramethylethylenediamine S/C Allyl Cross-coupling acetylacetonate Controlled potential electrolysis Oct BARF Benzyl turnover number TON SET tolyl Single electron transfer Room temperature dimethylformamide Dimethylsulfoxide TEMPO Non ferrocene Turnover frequency CH activation Phen PPN MoM Naph Naphthyl ALL Hex Hexamethylphosphoramide Cyclic voltammetry Polymethylhydrosiloxane Pent Pyridyl CO2 reduction Glassy carbon gas–liquid chromatography