The versatile ruthenium(II/III) tetraazamacrocycle complexes and their nitrosyl derivatives

Article ID	Journal	Published Year	Pages	File Type
1300883	Coordination Chemistry Reviews	2016	26 Pages	PDF

Abstract

- The versatility of tetraazamacrocycles, as cyclam, in ruthenium chemistry.
- Tetraazamacrocyle isomerization and/or oxidative dehydrogenation in ruthenium complexes.
- Chemical, photochemical, and biological aspects of tetraazamacrocycle ruthenium complexes.
- Structure and density functional theory calculations of tetraazamacrocycle ruthenium complexes.
- Spectral properties of tetraazamacrocycle ruthenium complexes.

Keywords

DOTA 1,4,7,10-Tetraazacyclododecane bpy LMCT Cyclam MLCT ACN tPA TD-DFT Cyclen ODQ TIM HUVEC BZn ACV SGC DAC Quinonediimine DTPA RASM ISN SAR TEOS PHI PDMS GLYMO Tetraazamacrocycle EDA [15]aneN4 THF TFMS inah 1H-[1,2,4]oxadiazolo[4,3-a]quinoxalin-1-one 1,10-Phenanthroline 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid 1,4,8,11-tetraazacyclotetradecane 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane 2-(4-carboxyphenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide 2-Aminomethylpyridine 2-Methylpyridine 2,2-Bipyridine 3-Glycidoxypropyltrimethoxysilane 4-Methylpyridine DMSO l-NAME ROS EDTA DIM Acetonitrile Benzonitrile Tame Tetrahydrofuran Energy decomposition analysis Terpy Tris(2-pyridylmethyl)amine pyz Ground state Lees Metastable state Diethylenetriaminepentaacetic acid Ruthenium Human umbilical vein endothelial cells Soluble guanylate cyclase Phen Ligand field Time-dependent density functional theory Nitrosyl Nitric oxide Hartree-Fock Polydimethylsiloxane Pyrazine Pyridine SNP NIC Reactive oxygen species