Hexamethylenetetramine: An old new building block for design of coordination polymers

Article ID	Journal	Published Year	Pages	File Type
1301103	Coordination Chemistry Reviews	2011	20 Pages	PDF

Abstract

âº Hexamethylenetetramine is a versatile building block for metal-organic networks. âº High diversity of topologies and structural motifs. âº Overview of synthetic methods, structural features and selected properties. âº Hmt is a good tool for further development of network materials.

Keywords

hMT NTA LMCT PDC FBA tPA MAL DCA PTA PROP phenylacetate TCM NITA DTB MTN R.T.PhaC adcA PTAS PBPD isobutyrate sh.DMA DMF DPA CTC Three-dimensional terephthalate THF dimethylacetamide 1,3,5-triaza-7-phosphaadamantane PMA Acetate Ligand-to-metal charge transfer high energy low energy Tar Tetrahydrofuran Tricyanomethanide Magnetic properties Self-assembly Malonate Water clusters DABCO Room temperature two-dimensional dimethylformamide dicyanamide Supramolecular structures Shoulder Coordination chemistry Photoluminescence Maleate Crystal engineering Male Nitrilotriacetate Hexamethylenetetramine Propionate Metal-organic frameworks (MOFs)one-dimensional