Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1301121 | Coordination Chemistry Reviews | 2011 | 8 Pages |
Abstract
ⶠOxides are the best-known compounds in solid state chemistry and, ideally, provide a paradigm for other types of materials. ⶠSulfides are not structurally related to oxides due to the larger covalency of the S2â anion compared to the O2â anion. ⶠHowever, for one-dimensional mixed-metal sulfides the ionic model can still describe structure and properties. ⶠA variety of magnetic and transport properties is found in one-dimensional sulfides. ⶠA rare example of low-spin configuration for tetrahedral Fe3+ in CsGa1âxFexS2. ⶠNegative magnetoresistance up to â¼10% recently reported in Ba2Co1âxZnxS3. ⶠLow-dimensional compounds, in general, are gaining more attention due to their similarities to nanowires.
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Authors
Mark R. Harrison, M. Grazia Francesconi,