| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1305405 | Inorganica Chimica Acta | 2016 | 9 Pages |
•Synthesis and characterisation of two photoluminescent cadmium(II) complexes with halosalicylaldimine Schiff base ligands.•Molecular structures on the basis of X-ray crystallography.•Supramolecular dimer via Br⋯Br interactions.•DFT calculations of supramolecular interactions.
Two new cadmium(II) complexes, [Cd(L1)(OOCCH3)(OH2)] (1), [Cd2(L2)2(μ-1,3-SCN)2(CH3OH)2] (2), have been synthesized using two halosalicylaldimine Schiff bases, HL1 and HL2 {where HL1 = 2-(2-(ethylamino)ethyliminomethyl)-4-bromophenol, and HL2 = 2-(2-(dimethylamino)ethyliminomethyl)-4-chlorophenol}, respectively. Both complexes have been characterized by elemental and spectral analysis and their structures have been confirmed by single crystal X-ray diffraction studies. Complex 1 is mononuclear and the cadmium(II) centre is apparently coordinated by a tridentate Schiff base, a water molecule and a bidentate chelating acetate. The acetate group could also be thought of as a single entity occupying just one stereochemical site as evident from the small value of chelate bite angle. Complex 2 is dinuclear and contain octahedral cadmium(II) bridged by double end-to-end thiocyanates. Supramolecular interactions in both complexes were also explored. The theoretical study, carried out using density functional theory (DFT) calculations, is devoted to the analysis of the interesting supramolecular assemblies in the solid state of the structures, paying special attention to hydrogen bonding interactions involving the coordinated solvent molecules.
Graphical abstractTwo new photoluminescent cadmium(II) complexes with halosalicylaldimine Schiff bases have been synthesized and characterized. The structures have been confirmed by single crystal X-ray analysis. Supramolecular interactions in both complexes have been explored and analysed by means of DFT calculations.Figure optionsDownload full-size imageDownload as PowerPoint slide
