Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1305997 | Inorganica Chimica Acta | 2012 | 7 Pages |
Abstract
⺠VO2+ dinuclear complex [(VO)2(μ2-SO4)2(dtb-bpy)2(MeOH)2]·4MeOH (1) was obtained. ⺠ESR spectra in CH2Cl2 solution showed the dimerization of complex molecule 1. ⺠Reaction of the source compound with NaPiv produced [(VO)2(μ2-O)2(μ2-SO4)(dtb-bpy)2]·2MeCN (2). ⺠Cyclic voltammogram sowed that vanadium in 2 has the oxidation state +5.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Evgenia S. Bazhina, Marina E. Nikiforova, Grigory G. Aleksandrov, Nikolay N. Efimov, Helena A. Ugolkova, Oleg M. Nikitin, Tatiana V. Magdesieva, Artem S. Bogomyakov, Vadim V. Minin, Aleksei A. Sidorov, Vladimir M. Novotortsev, Igor L. Eremenko,