| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1306109 | Inorganica Chimica Acta | 2012 | 7 Pages |
Abstract
⺠Cu(en)2SiF6 (1) and [Cu(dmen)2(H2O)]SiF6 (2) were prepared and characterized. ⺠Chain-like and ionic crystal structures are formed by 1 and 2, resp. ⺠Hydrogen bonds play important role in packing and magnetism in both structures. ⺠EPR and magnetic data revealed 2D AF magnetic structure in both 1 and 2. ⺠Rectangular AF magnetic model was suggested for description of 2.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
J. HanÃková, J. Äernák, J. Kuchár, E. Äižmár,
![First Page Preview: Cu(en)2SiF6 and [Cu(dmen)2(H2O)]SiF6 (en = 1,2-diaminoethane; dmen = N,N-dimethyl-1,2-diaminoethane): Preparations, crystal structures, spectroscopic properties and hydrogen bonding mediated magnetism Cu(en)2SiF6 and [Cu(dmen)2(H2O)]SiF6 (en = 1,2-diaminoethane; dmen = N,N-dimethyl-1,2-diaminoethane): Preparations, crystal structures, spectroscopic properties and hydrogen bonding mediated magnetism](/preview/png/1306109.png)