| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1306328 | Inorganica Chimica Acta | 2011 | 5 Pages |
The Suzuki–Miyaura reaction of various aryl halides using [Pd{C6H2(CH2CH2NH2)–(OMe)2,3,4} (μ-Br)]2 have been investigated. This orthopalladated complex is an efficient, stable and non-sensitive to air and moisture catalyst for the hetrocoupling reaction in DMF as the reaction solvent at 130 °C. The combination of dimeric complex as homogenous catalyst and microwave irradiation can be very useful and efficient methods in organic synthesis, so the application of microwave irradiation have been investigated using homogenous dimeric complex [Pd{C6H2(CH2CH2NH2)–(OMe)2,3,4} (μ-Br)]2. Application of dimeric complex as catalyst caused to produce the desired coupling products and the using of microwave irradiation improving the yields of the reactions and shortening the reaction times.
Graphical abstractThe Suzuki–Miyaura reaction of various aryl halides using palladacycle A has been investigated. This orthopalladated complex is a proficient air and moisture catalyst for the coupling reaction as efficient catalytic in DMF as the reaction solvent at 130 °C. The application of microwave irradiation caused to produce the desire products in shorter reaction time in comparison to conventional heating method with good yields.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights►Reaction under microwave conditions with high yield and short reaction times. ► Efficient palladacycle reagent. ► The Suzuki–Miyaura reaction of various aryl halides using palladacycle A has been investigated. ► This orthopalladated complex is a proficient air and moisture catalyst for the coupling reaction.
