Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1306411 | Inorganica Chimica Acta | 2016 | 8 Pages |
Abstract
Structural analysis of four coordinated (ONSP) nickel(II) complexes obtained from 3-Bromo-5-chloro-2-hydroxyacetophenone-N4-hexyl (L1H2), cyclohexyl (L2H2) and phenyl (L3H2)-thiosemicarbazones were by spectroscopic and single crystal X-ray diffraction methods. Basic electrochemical parameters of the ligand and complexes were measured. Electrogenerated species of the complexes, [Ni(L1)(PPh3)] (1), [Ni(L2H)(PPh3)]·Cl (2) and [Ni(L3)(PPh3)]·C2H5OH (3), were determined using in situ spectroelectrochemical methode.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Åükriye Güveli, Namık Ãzdemir, Atıf Koca, Tülay Bal-Demirci, Bahri Ãlküseven,