| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1306676 | Inorganica Chimica Acta | 2010 | 7 Pages |
Abstract
The chemical detection of sigma-carbon-metal bonds in solutions of organometallics can be achieved by deuteriodemetallation with electrophilic D-A reagents (A = OD, OAc), but with transition metals their thermal and light sensitivity requires low temperatures in the dark. Transition metal carbenes can be detected by cycloadditions with alkynes or nitriles.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
John J. Eisch,