| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1306695 | Inorganica Chimica Acta | 2010 | 6 Pages |
The dinuclear V(V) complexes (VOL)2O (L = SAE (1), SAMP (2), SAP (3)) have been synthesized from VO(acac)2 and the corresponding tridentate ligands LH2 in methanol under reflux conditions and subsequent air oxidation in organic solvent. They have been characterized by IR and NMR spectroscopy, by thermogravimetric analysis, and by single crystal X-ray diffraction for 1 and 2. DFT calculations were carried out for a better understanding of the vibrational pattern, principally the V–O related vibrations. Complex [VO(SAP)]2O (3) catalyzes the epoxidation of cyclooctene by TBHP in water in the absence of any added solvent with good selectivity.
Graphical abstractComplexes [VOL]2O (L = ONO tridentate ligands, L = SAE, SAMP, SAP) are shown to be good pre-catalysts for cyclooctene epoxidation using aqueous TBHP without extra added organic solvent.Figure optionsDownload full-size imageDownload as PowerPoint slide
