Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1306804 | Inorganica Chimica Acta | 2010 | 8 Pages |
Abstract
The synthesis and structural studies of three novel Hg(II) complexes, molecular and polymeric, produced with the use of a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand, are reported. The distinctly different compounds were isolated from otherwise identical reaction mixtures at different reaction temperatures. The salient coordination modes of the cluster-bound PTA ligand, including one for which there is no literature precedent, are discussed, together with some discussion of the profound temperature effects observed on the identity of the products.
Related Topics
Physical Sciences and Engineering
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Authors
Xiaoyan Tu, Huong Truong, Gary S. Nichol, Zhiping Zheng,